Rearrangement reactions in solid-state organic compounds

Understanding solid/solid organic reactions.

The concept of an organic reaction between two macroscopic solid particles is investigated. Thus, we study several reactions that have been recently reported to proceed "in the solid phase" and clearly show that, in most cases, grinding the two solid reactants together results in the formation of a liquid phase. This is true both for catalytic transformations (e.g., aldol condensations and olig...

Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)

Nuclear Magnetic Resonance (NMR) spectroscopy is a well-established method for the investigation of various types of porous materials. During the past decade, metal–organic frameworks have attracted increasing research interest. Solid-state NMR spectroscopy has rapidly evolved into an important tool for the study of the structure, dynamics and flexibility of these materials, as well as for the ...

Electrode Reactions of Organic Compounds

The last Faraday Society Discussions on Electrode Processes were held in 1947 and marked the onset of an extensive fruitful post-war development of fast reaction techniques in electrochemistry. Considerable information has since been obtained on rate constants of simple inorganic electron transfers, paralleling a similar development in homogeneous reactions, and on electron transfer theory. A t...

Organic–inorganic supramolecular solid catalyst boosts organic reactions in water

Coordination polymers and metal-organic frameworks are appealing as synthetic hosts for mediating chemical reactions. Here we report the preparation of a mesoscopic metal-organic structure based on single-layer assembly of aluminium chains and organic alkylaryl spacers. The material markedly accelerates condensation reactions in water in the absence of acid or base catalyst, as well as organoca...

Functional diversity in templated solid state reactions